Removal of cadmium from contaminated soil using iron (III) oxide nanoparticles stabilized with polyacrylic acid
Abstract
The aim of this study is to evaluate the effect of Fe3O4 nanoparticle, stabilized with polyacrylic acid on cadmium removal from the contaminated soils. To investigate the effect of important parameters, including nanoparticle concentration, pH, contact time, and the ratio of contaminated soil mass to nanofluid volume, several batch tests were performed. The maximum removal rate (100%) of cadmium was obtained in the following conditions: nanofluid concentration = 500 ppm, pH = 6.5, contact time = 24 hr and the ratio of contaminated soil mass (gr) to nanofluid volume (mL) = 1:150. Results of selective sequential extraction tests showed that the distribution of cadmium in different fractions of the soil was carbonates, oxides and hydroxides, residual fraction, exchangeable, and organic matter respectively. The tendency of nanoparticles for removal of Cd2+ from the soil fractions was in the order of: exchangeable > carbonates > oxides and hydroxides > organic matter > residual.
Keyword : soil contamination, iron (III) oxide nanoparticle, polyacrylic acid, cadmium removal, selective sequential extraction
How to Cite
Mohamadiun, M., Dahrazma, B., Saghravani, S. F., & Khodadadi Darban, A. (2018). Removal of cadmium from contaminated soil using iron (III) oxide nanoparticles stabilized with polyacrylic acid. Journal of Environmental Engineering and Landscape Management, 26(2), 98-106. https://doi.org/10.3846/16486897.2017.1364645
This work is licensed under a Creative Commons Attribution 4.0 International License.
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He, F.; Zhao, D. Y. 2005. Preparation and characterization of a new class of starch-stabilized biometallic nanoparticles for degration of chlorinated hydrocarbons in water, Environmental Science and Technology 39: 3314–3320. https://doi.org/10.1021/es048743y
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Hseu, Z. Y. 2006. Concentration and distribution of chromium and nickel fractions along a serpentinitic toposequence, Soil Science 171(4): 341–353. https://doi.org/10.1097/01.ss.0000209354.68783.f3
Huang, Z. Y.; Li, J.; Cao, Y. L.; Cai, C.; Zhang, Z. 2016. Behaviors of exogenous Pb in P-based Amended soil investigated with isotopic labeling method coupled with tessier approach, Geoderma 264: 126–131. https://doi.org/10.1016/j.geoderma.2015.10.013
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Li, J.; Sun, Y.; Yin, Y.; Ji, R.; Wu, J.; Wang, X.; Guo, H. 2010. Ethyl lactate-EDTA composite system enhances the remediation of the cadmium-contaminated soil by autochthonous willow (Salix× aureo-pendula CL ‘J1011’) in the lower reaches of the Yangtze River, Journal of Hazardous Materials 181(1): 673–678. https://doi.org/10.1016/j.jhazmat.2010.05.065
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Liu. H.; Chen, T.; Xie, Q.; Zou, X. 2015. The functionalization of limonite to prepare NZVI and its application in decomposition of p-nitrophenol, Journal of Nanoparticle Research 17: 374–391. https://doi.org/10.1007/s11051-015-3171-6
Martínez-Fernández, D.; Bingöl, D.; Komárek, M. 2014. Trace elements and nutrients adsorption onto nano-maghemite in a contaminated-soil solution: a geochemical/statistical approach, Journal of Hazardous Materials 276: 271–277. https://doi.org/10.1016/j.jhazmat.2014.05.043
McLaren, R. G.; Crawford, D. 1973. Studies on soil copper: the fractionation of copper in soils, Journal of Soil Science 24: 172–179. https://doi.org/10.1111/j.1365-2389.1973.tb00753.x
Mulligan, C. N.; Dahrazma, B. 2003. Use of selective sequential extraction for the remediation of contaminated sediments, ASTM STP 1442: 208–223. https://doi.org/10.1520/STP11564S
Nasiri, J.; Gholami, A.; Ebrahimi, P. 2013. Removal of Cadmium from soil resources using stabilized Zero-Valent Iron Nanoparticles, Journal of Civil Engineering and Urbanism 3(6): 338–341.
Nutt, M. O.; Hughes, J. B.; Wong, M. S. 2005. Designing Pd-on-Au bimetallic nanoparticle catalysts for trichloroethene hydrodechlorination, Environmental Science and Technology 39: 1346–1353. https://doi.org/10.1021/es048560b
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